Poisons: Their Effects and Detection A Manual for the Use of Analytical Chemists and Experts
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POISONS: THEIR EFFECTS AND DETECTION. A MANUAL FOR THE USE OF ANALYTICAL CHEMISTS AND EXPERTS.
PREFACE TO THE THIRD EDITION.
CONTENTS.
LIST OF ILLUSTRATIONS.
PART I.—INTRODUCTORY.
I.—The Old Poison-Lore.
II.—Growth and Development of the Modern Methods of Chemically Detecting Poisons.
PART II.
I.—Definition of Poison.
II.—Classification of Poisons.
A. Poisons causing Death immediately, or in a few minutes.
B. Irritant Poisons (symptoms mainly pain, vomiting, and purging).
C. Irritant and Narcotic Poisons (symptoms those of an irritant nature, with the addition of more or less pronounced cerebral indications).
D. Poisons more especially affecting the Nervous System.
I. POISONS WHICH CAUSE COARSE ANATOMICAL CHANGES OF THE ORGANS.
II. BLOOD POISONS.
III. POISONS WHICH KILL WITHOUT THE PRODUCTION OF COARSE ANATOMICAL CHANGE.
IV. POISONOUS PRODUCTS OF TISSUE CHANGE.
A.—POISONOUS GASES.
B.—ACIDS AND ALKALIES.
C.—POISONOUS SUBSTANCES CAPABLE OF BEING SEPARATED BY DISTILLATION FROM EITHER NEUTRAL OR ACID LIQUIDS.
D.—ALKALOIDS AND POISONOUS VEGETABLE PRINCIPLES SEPARATED FOR THE MOST PART BY ALCOHOLIC SOLVENTS.
E.—POISONS DERIVED FROM LIVING OR DEAD ANIMAL SUBSTANCES.
F.—THE OXALIC ACID GROUP.
G.—INORGANIC POISONS.
A. Poisons causing Death immediately, or in a few minutes.
B. Irritant Poisons (symptoms mainly pain, vomiting, and purging).
C. Irritant and Narcotic Poisons (symptoms those of an irritant nature, with the addition of more or less pronounced cerebral indications).
D. Poisons more especially affecting the Nervous System.
I. POISONS WHICH CAUSE COARSE ANATOMICAL CHANGES OF THE ORGANS.
II. BLOOD POISONS.
III. POISONS WHICH KILL WITHOUT THE PRODUCTION OF COARSE ANATOMICAL CHANGE.
IV. POISONOUS PRODUCTS OF TISSUE CHANGE.
A.—POISONOUS GASES.
B.—ACIDS AND ALKALIES.
C.—POISONOUS SUBSTANCES CAPABLE OF BEING SEPARATED BY DISTILLATION FROM EITHER NEUTRAL OR ACID LIQUIDS.
D.—ALKALOIDS AND POISONOUS VEGETABLE PRINCIPLES SEPARATED FOR THE MOST PART BY ALCOHOLIC SOLVENTS.
E.—POISONS DERIVED FROM LIVING OR DEAD ANIMAL SUBSTANCES.
F.—THE OXALIC ACID GROUP.
G.—INORGANIC POISONS.
III.—Statistics.
Criminal Poisoning.
IV.—The Connection between Toxic Action and Chemical Composition.
Criminal Poisoning.
IV.—The Connection between Toxic Action and Chemical Composition.
V.—Life-Tests; or the Identification of Poison by Experiments on Animals.
VI.—General Method of Procedure in Searching for Poison.
AUTENRIETH’S GENERAL PROCESS.
I. SUBSTANCES SEPARATED BY DISTILLATION.
II. ORGANIC POISONS NOT VOLATILE IN ACID SOLUTION.
III. METALS.
AUTENRIETH’S GENERAL PROCESS.
I. SUBSTANCES SEPARATED BY DISTILLATION.
II. ORGANIC POISONS NOT VOLATILE IN ACID SOLUTION.
III. METALS.
VII.—The Spectroscope as an aid to the Identification of certain Poisons.
Examination of Blood, or of Blood-Stains.
Examination of Blood, or of Blood-Stains.
PART III.—POISONOUS GASES: CARBON MONOXIDE—CHLORINE—HYDRIC SULPHIDE.
I.—Carbon Monoxide.
II.—Chlorine.
III.—Hydric Sulphide (Sulphuretted Hydrogen).
PART IV.—ACIDS AND ALKALIES.
I.—Sulphuric Acid.
Detection and Estimation of Free Sulphuric Acid.
Detection and Estimation of Free Sulphuric Acid.
II.—Hydrochloric Acid.
Detection and Estimation of Free Hydrochloric Acid.
Detection and Estimation of Free Hydrochloric Acid.
III.—Nitric Acid.
IV.—Acetic Acid.
V.—Ammonia.
VI.—Caustic Potash and Soda.
VII.—Neutral Sodium, Potassium, and Ammonium Salts.
Detection and Estimation of Potassic Chlorate.
Toxicological Detection of Alkali Salts.
Detection and Estimation of Potassic Chlorate.
Toxicological Detection of Alkali Salts.
PART V.—MORE OR LESS VOLATILE POISONOUS SUBSTANCES CAPABLE OF BEING SEPARATED BY DISTILLATION FROM NEUTRAL OR ACID LIQUIDS.
I.—Hydrocarbons.
1. PETROLEUM.
2. COAL-TAR-NAPHTHA—BENZENE.
3. TERPENES—ESSENTIAL OILS—OIL OF TURPENTINE.
4. OIL OF TURPENTINE—SPIRIT OF TURPENTINE—“TURPS.”
1. PETROLEUM.
2. COAL-TAR-NAPHTHA—BENZENE.
3. TERPENES—ESSENTIAL OILS—OIL OF TURPENTINE.
4. OIL OF TURPENTINE—SPIRIT OF TURPENTINE—“TURPS.”
II.—Camphor.
III.—Alcohols.
1. ETHYLIC ALCOHOL.
2. AMYLIC ALCOHOL.
1. ETHYLIC ALCOHOL.
2. AMYLIC ALCOHOL.
IV.—Ether.
V.—Chloroform.
Poisonous Effects of Chloroform.
Poisonous Effects of Chloroform.
VI.—Other Anæsthetics.
VII.—Chloral.
VIII.—Bisulphide of Carbon.
IX.—The Tar Acids—Phenol—Cresol.
Tests for Carbolic Acid.
Tests for Carbolic Acid.
X.—Nitro-Benzene.
XI.—Dinitro-benzol.
XII.—Hydrocyanic Acid.
Poisonous Cyanides other than Hydric and Potassic Cyanides.
Poisonous Cyanides other than Hydric and Potassic Cyanides.
XIII.—Phosphorus.
PART VI.—ALKALOIDS AND POISONOUS VEGETABLE PRINCIPLES SEPARATED FOR THE MOST PART BY ALCOHOLIC SOLVENTS.
DIVISION I.—VEGETABLE ALKALOIDS.
I.—General Methods of Testing and Extracting Alkaloids.
II.—Liquid Volatile Alkaloids.
III.—The Opium Group of Alkaloids.
IV.—The Strychnine or Tetanus-Producing[422] Group of Alkaloids.
V.—The Aconite Group of Alkaloids.
VI.—The Mydriatic Group of Alkaloids—Atropine—Hyoscyamine—Solanine—Cytisine.
VII.—The Alkaloids of the Veratrums.
VIII.—Physostigmine.
IX.—Pilocarpine.
X.—Taxine.
XI.—Curarine.
XII.—Colchicine.
XIII.—Muscarine and the Active Principles of Certain Fungi.
I.—General Methods of Testing and Extracting Alkaloids.
II.—Liquid Volatile Alkaloids.
III.—The Opium Group of Alkaloids.
IV.—The Strychnine or Tetanus-Producing[422] Group of Alkaloids.
V.—The Aconite Group of Alkaloids.
VI.—The Mydriatic Group of Alkaloids—Atropine—Hyoscyamine—Solanine—Cytisine.
VII.—The Alkaloids of the Veratrums.
VIII.—Physostigmine.
IX.—Pilocarpine.
X.—Taxine.
XI.—Curarine.
XII.—Colchicine.
XIII.—Muscarine and the Active Principles of Certain Fungi.
DIVISION II.—GLUCOSIDES.
I.—Digitalis Group.
II.—Other Poisonous Glucosides Acting on the Heart.
III.—Saponin—Saponin Substances.
I.—Digitalis Group.
II.—Other Poisonous Glucosides Acting on the Heart.
III.—Saponin—Saponin Substances.
DIVISION III.—CERTAIN POISONOUS ANHYDRIDES OF ORGANIC ACIDS.
I.—Santonin.
II.—Mezereon.
I.—Santonin.
II.—Mezereon.
DIVISION IV.—VARIOUS VEGETABLE POISONOUS PRINCIPLES—NOT ADMITTING OF CLASSIFICATION UNDER THE PREVIOUS THREE DIVISIONS.
I.—Ergot of Rye.
II.—Picrotoxin, the Active Principle of the Cocculus indicus (Indian Berry, Levant Nut).
III.—The Poison of Illicium Religiosum—A Japanese Plant.
IV.—Picric Acid and Picrates.
V.—Cicutoxin.
VI.—Æthusa Cynapium (Fool’s Parsley).
VII.—Œnanthe Crocata.
VIII.—Oil of Savin.
IX.—Croton Oil.
X.—The Toxalbumins of Castor-Oil Seeds and of Abrus.
XI.—Ictrogen.
XII.—Cotton Seeds.
XIII.—Lathyrus Sativus.
XIV.—Arum—Bryony—Locust Tree—Male Fern.
I.—Ergot of Rye.
II.—Picrotoxin, the Active Principle of the Cocculus indicus (Indian Berry, Levant Nut).
III.—The Poison of Illicium Religiosum—A Japanese Plant.
IV.—Picric Acid and Picrates.
V.—Cicutoxin.
VI.—Æthusa Cynapium (Fool’s Parsley).
VII.—Œnanthe Crocata.
VIII.—Oil of Savin.
IX.—Croton Oil.
X.—The Toxalbumins of Castor-Oil Seeds and of Abrus.
XI.—Ictrogen.
XII.—Cotton Seeds.
XIII.—Lathyrus Sativus.
XIV.—Arum—Bryony—Locust Tree—Male Fern.
PART VII.—POISONS DERIVED FROM LIVING OR DEAD ANIMAL SUBSTANCES.
DIVISION I.—POISONS SECRETED BY LIVING ANIMALS.
I.—Poisonous Amphibia.
II.—The Poison of the Scorpion.
III.—Poisonous Fish.
IV.—Poisonous Spiders and Other Insects.
V.—Snake Poison.
I.—Poisonous Amphibia.
II.—The Poison of the Scorpion.
III.—Poisonous Fish.
IV.—Poisonous Spiders and Other Insects.
V.—Snake Poison.
DIVISION II.—PTOMAINES—TOXINES.
Isolation of Ptomaines.
Diamines.
Isolation of Ptomaines.
Diamines.
DIVISION III.—FOOD POISONING.
PART VIII.—THE OXALIC ACID GROUP OF POISONS.
CERTAIN OXALIC BASES—OXALMETHYLINE—OXALPROPYLINE.
PART IX.—INORGANIC POISONS.
I.—PRECIPITATED FROM A HYDROCHLORIC ACID SOLUTION BY HYDRIC SULPHIDE—PRECIPITATE YELLOW OR ORANGE.[700] Arsenic—Antimony—Cadmium.
1. ARSENIC.
2. ANTIMONY.
3. CADMIUM.
1. ARSENIC.
2. ANTIMONY.
3. CADMIUM.
II.—PRECIPITATED BY HYDRIC SULPHIDE IN HYDROCHLORIC ACID SOLUTION—BLACK. Lead—Copper—Bismuth—Silver—Mercury.
1. LEAD.
2. COPPER.
3. BISMUTH.
4. SILVER.
5. MERCURY.
1. LEAD.
2. COPPER.
3. BISMUTH.
4. SILVER.
5. MERCURY.
III.—PRECIPITATED BY HYDRIC SULPHIDE FROM A NEUTRAL SOLUTION. Zinc—Nickel—Cobalt.
1. ZINC.
2. NICKEL—COBALT.
1. ZINC.
2. NICKEL—COBALT.
IV.—PRECIPITATED BY AMMONIUM SULPHIDE. Iron—Chromium—Thallium—Aluminium—Uranium.
1. IRON.
2. CHROMIUM.
3. THALLIUM.
4. ALUMINIUM.
5. URANIUM.
1. IRON.
2. CHROMIUM.
3. THALLIUM.
4. ALUMINIUM.
5. URANIUM.
V.—ALKALINE EARTHS.
Barium.
Barium.
APPENDIX.
Treatment by Antidotes or otherwise of Cases of Poisoning.
I. Instruments:—
II. Emetics:—
III. Antidotes:—
I. Instruments:—
II. Emetics:—
III. Antidotes:—
TREATMENT.
DOMESTIC READY REMEDIES FOR POISONING.
INDEX.
Transcriber’s Notes
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